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[1] [2]

1. Synthesis and characterisation of Hf(thd)2X2 derivatives [X=N(SiMe3)2, OSiMe3 and OSitBuMe2] as precursors for MOCVD of hafnium silicate films. Hubert-Pfalzgraf, Liliane G.; Touati, Nadia; Pasko, Sergej V.; Vaissermann, J.; Abrutis, Adulfas. Polyhedron vol. 24 issue 18 December 8, 2005. p. 3066-3073

 Hafnium β-diketonatochlorides HfCl2(thd)2 (1), HfCl(thd)3 (2) as well as β-diketonato-silylamide and/or siloxide… (more)

Keywords: Silylamide

DOI: 10.1016/j.poly.2005.06.036. ISSN: 0277-5387.

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2. β-SiH agostic bonding in sterically crowded lanthanidocene silylamide complexes. Klimpel, Michael G.; Görlitzer, Hans W.; Tafipolsky, Maxim; Spiegler, Michael; Scherer, Wolfgang; Anwander, Reiner. Journal of Organometallic Chemistry vol. 647 issue 1-2 March 15, 2002. p. 236 - 244

 The synthesis as well as the spectroscopic and structural characterization of mononuclear metallocene… (more)

Keywords: Silylamide route

ISSN: 0022-328X.

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3. DIBAH-Mediated Amide/Hydride Transformation in ansa-Lanthanidocene(III) Complexes. Klimpel, Michael G.; Sirsch, Peter; Scherer, Wolfgang; Anwander, Reiner. Angewandte Chemie vol. 115 issue 5 February 3, 2003. p. 594 - 597

No Abstract

Keywords: Silylamide

DOI: 10.1002/ange.200390133. ISSN: 0044-8249.

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4. DIBAH-Mediated Amide/Hydride Transformation in ansa-Lanthanidocene(III) Complexes. Klimpel, Michael G.; Sirsch, Peter; Scherer, Wolfgang; Anwander, Reiner. Angewandte Chemie International Edition vol. 42 issue 5 February 3, 2003. p. 574 - 577

No Abstract

Keywords: silylamide

DOI: 10.1002/anie.200390165. ISSN: 1433-7851.

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5. Synthesis of the sterically encumbering terphenyl silyl and alkyl amines Formula Not Shown (R=Me and SiMe3), their lithium derivatives Formula Not Shown , and the tertiary amine Formula Not Shown. Wright, Robert J.; Steiner, Jochen; Beaini, Samar; Power, Philip P. Inorganica Chimica Acta vol. 359 issue 6 April 10, 2006. p. 1939-1946

 Reaction of the terphenyl derivative Formula Not Shown (synthesized in “one pot” directly… (more)

Keywords: Bis-silylamides

DOI: 10.1016/j.ica.2005.10.015. ISSN: 0020-1693.

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6. 2,4-Disila-1,3,5-oxadiazin, Cyclodisilazan-Carbonsäure-silylamid und -silylester. Armbruster, Nina; Jaschke, Bettina; Kingebiel, Uwe; Voit, Claudia; dall’ Antonia, Fabio; Herbst-Irmer, Regine. Zeitschrift für anorganische und allgemeine Chemie vol. 634 issue 11 September 2008. p. 1937 - 1942

 The lithium salts of the Me3Si- as well as Me3Si- and Me2SiF-substituted Cyclotrisilazanes… (more)

Keywords: Cyclodisilazane-silylamide

DOI: 10.1002/zaac.200800205. ISSN: 0044-2313.

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7. The Danishefsky Hetero Diels–Alder Reaction Mediated by Organolanthanide-Modified Mesoporous Silicate MCM-41. Gerstberger, Gisela; Palm, Clemens; Anwander, Reiner. Chemistry - A European Journal vol. 5 issue 3 March 1, 1999. p. 997 - 1005

 Ease of separation, recovery, and reuseability characterize the hybrid catalysts described by comparison… (more)

Keywords: Silylamides

DOI: 10.1002/(SICI)1521-3765(19990301)5:3<997::AID-CHEM997>3.0.CO;2-D. ISSN: 0947-6539.

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8. Yttrium half-sandwich complexes bearing the 2-(N,N-dimethylamino)ethyl-tetramethylcyclopentadienyl ligand. Jende, Lars N.; Maichle-Mössmer, Cäcilia; Schädle, Christoph; Anwander, Reiner. Journal of Organometallic Chemistry vol. 744 November 1, 2013. p. 74-81

 The synthesis of bis(dimethylsilyl)amide and dimethyl half-sandwich complexes of yttrium bearing the 2-(N,N-dimethylamino)ethyl-tetramethylcyclopentadienyl… (more)

Keywords: Silylamide

DOI: 10.1016/j.jorganchem.2013.05.002. ISSN: 0022-328X.

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9. Cerium(III/IV) Formamidinate Chemistry, and a Stable Cerium(IV) Diolate. Werner, Daniel; Deacon, Glen B.; Junk, Peter C.; Anwander, Reiner. Chemistry – A European Journal vol. 20 issue 15 April 7, 2014. p. 4426-4438

 Four new cerium(III) formamidinate complexes comprising [Ce(p-TolForm)3], [Ce(DFForm)3(thf)2], [Ce(DFForm)3], and [Ce(EtForm)3] were synthesized… (more)

Keywords: silylamide

DOI: 10.1002/chem.201304582. ISSN: 0947-6539.

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10. Syntheses and X-ray crystal structures of monomeric zinc and mercury bis(silylamides). Tang, Yongjun; Felix, Ana M.; Boro, Brian J.; Zakharov, Lev N.; Rheingold, Arnold L.; Kemp, Richard A. Polyhedron vol. 24 issue 9 June 28, 2005. p. 1093-1100

 Lithium amides Li[N(SiMe3)(R)] (R=–SiPh2tBu and adamantyl), generated in situ from the reaction of… (more)

Keywords: Zn silylamides; Hg silylamides

DOI: 10.1016/j.poly.2005.02.029. ISSN: 0277-5387.

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11. Synthesis and structure of lithium amides and solvated derivatives containing bulky bis(silylamide) ligands. Tang, Yongjun; Zakharov, Lev N.; Rheingold, Arnold L.; Kemp, Richard A. Polyhedron vol. 24 issue 13 September 15, 2005. p. 1739-1748

 Dimeric, non-solvated lithium amides containing the sterically crowded silylamide ligands {Li[N(SiMe3)(SiPh2tBu)]}2 (1)… (more)

Keywords: Lithium (bis)silylamides

DOI: 10.1016/j.poly.2005.05.006. ISSN: 0277-5387.

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12. The First Oligomeric Samarium(II) Silylamide: Coordinative Saturation through Agostic Sm···SiH Interactions. Nagl, Iris; Scherer, Wolfgang; Tafipolsky, Maxim; Anwander, Reiner. European Journal of Inorganic Chemistry vol. 1999 issue 9 September 1999. p. 1405 - 1407

 Sm[N(SiMe3)2]2(thf)2 reacts with 1,1,3,3-tetramethyldisilazane by a transsilylamination reaction to form the hexane-soluble Sm[N(SiHMe2)2]2(thf)x… (more)

Keywords: Silylamide

DOI: 10.1002/(SICI)1099-0682(199909)1999:9<1405::AID-EJIC1405>3.0.CO;2-#. ISSN: 1434-1948.

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13. Synthesis and Structure of Aminopyridinato-Stabilized Yttrium and Lanthanum Amides and Their Reactivity towards Alkylaluminium Compounds. Döring, Christian; Kempe, Rhett. European Journal of Inorganic Chemistry vol. 2009 issue 3 January 2009. p. 412 - 418

 A series of aminopyridinato-stabilized (amido)lanthanide complexes has been synthesized and characterized. The bulky… (more)

Keywords: Silylamide route

DOI: 10.1002/ejic.200800934. ISSN: 1434-1948.

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14. Silylated amino-triazines: new ligands with potential multi-coordination modes. Parker, Bree; Son, David Y. Inorganic Chemistry Communications vol. 5 issue 7 July, 2002. p. 516-518

 Melamine (1a), 2,4-diamino-6-phenyl-1,3,5-triazine (1b), and 2,4-diamino-6-methyl-triazine (1c) react with chlorotrimethylsilane and triethylamine in… (more)

Keywords: Silylamide

ISSN: 1387-7003.

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15. Synthesis of substituted 1,1′-diaminoferrocenes from cyclo-2-pentene imines. Nikolaides, Katharina R.; Hoffmann, Stephan D.; Eppinger, Jörg. Journal of Organometallic Chemistry vol. 693 issue 13 June 15, 2008. p. 2223-2230

 Condensation of anilines and primary aliphatic amines with 3,4-diphenylcyclo-2-pentenone leads to the corresponding… (more)

Keywords: Silylamide route

DOI: 10.1016/j.jorganchem.2007.12.020. ISSN: 0022-328X.

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16. Lokale Lithiumfluktuationen mit niedriger Aktivierungsenergie in zwei Festkörperphasen des Lithiumsilylamids [(Me2SiNtBuLi)2O]2. Veith, Michael; Zimmer, Michael; Huch, Volker. Zeitschrift für anorganische und allgemeine Chemie vol. 635 issue 4-5 April 2009. p. 674 - 681

 Local Lithium Fluctuations with low Activation Energies in two solid Phases of the… (more)

Keywords: Silylamides

DOI: 10.1002/zaac.200900015. ISSN: 0044-2313.

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17. Darstellung, Kristall- und Molekülstruktur eines zwölfgliedrigen N,N′-Di-Lithium-cyclosiloxazans [Me2SiOSiMe2N(Li)SiMe2O]2. Veith, Michael; Rammo, Andreas; Heim, Ralf; Huch, Volker. Zeitschrift für anorganische und allgemeine Chemie vol. 636 issue 2 February 2010. p. 320 - 324

 The twelve membered and eighteen membered cyclosiloxazanes [Me2SiOSiMe2N(H)SiMe2O]2 (3) and [Me2SiOSiMe2N(H)SiMe2O]3 (4) have… (more)

Keywords: Silylamides

DOI: 10.1002/zaac.200900366. ISSN: 0044-2313.

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18. Bis(fluor-diisopropylsilyl)amin als Baustein anorganischer Heterocyclen. Marcus, L.; Klingebiel, U.; Lameyer, L.; Stalke, D. Zeitschrift für anorganische und allgemeine Chemie vol. 624 issue 6 June, 1998. p. 1041 - 1045

  Bis(fluor-diisopropylsilyl)amin I reagiert mit LiC4H9 im Molverhältnis 1 : 1 zum Lithiumderivat II, (iPr2SiF)2NLi… (more)

Keywords: lithium-silylamide

DOI: 10.1002/1521-3749(199806)624:6<1041::AID-ZAAC1041>3.0.CO;2-G. ISSN: 0044-2313.

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19. Lokale Lithiumfluktuationen mit niedriger Aktivierungsenergie in zwei Festkörperphasen des Lithiumsilylamids [(Me2SiNtBuLi)2O]2. Veith, Michael; Zimmer, Michael; Huch, Volker. Zeitschrift für anorganische und allgemeine Chemie vol. 635 issue 4-5 April 2009. p. 674 - 681

 Local Lithium Fluctuations with low Activation Energies in two solid Phases of the… (more)

Keywords: Lithium; NMR spectroscopy; Metal dynamics; Local metal movements; Silylamides

DOI: 10.1002/zaac.200900015. ISSN: 0044-2313.

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20. Darstellung, Kristall- und Molekülstruktur eines zwölfgliedrigen N,N′-Di-Lithium-cyclosiloxazans [Me2SiOSiMe2N(Li)SiMe2O]2. Veith, Michael; Rammo, Andreas; Heim, Ralf; Huch, Volker. Zeitschrift für anorganische und allgemeine Chemie vol. 636 issue 2 February 2010. p. 320 - 324

 The twelve membered and eighteen membered cyclosiloxazanes [Me2SiOSiMe2N(H)SiMe2O]2 (3) and [Me2SiOSiMe2N(H)SiMe2O]3 (4) have… (more)

Keywords: Lithium; Silylamides; X-ray diffraction; Siloxazanes; Cyclosiloxanes

DOI: 10.1002/zaac.200900366. ISSN: 0044-2313.

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21. Synthesis and structural characterization of solvated calcium amides containing bulky silylamide ligands. Tang, Yongjun; Zakharov, Lev N.; Kassel, W. Scott; Rheingold, Arnold L.; Kemp, Richard A. Inorganica Chimica Acta vol. 358 issue 6 March 30, 2005. p. 2014-2022

 A series of solvated calcium bis(amides) with the general formula Ca[N(R)(SiMe3)]2(solv)x (R=–SiMe2t-Bu, –SiPh2t-Bu,… (more)

Keywords: Silylamide

DOI: 10.1016/j.ica.2004.12.019. ISSN: 0020-1693.

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22. Siloxanes and silylamines with fluoromethyl-methylsilicon groups: X-ray study of [CH2F(CH3)SiO]4. Beckers, Helmut; Brauer, David J.; Bürger, Hans; Gielen, Ralf; Moritz, Peter. Journal of Organometallic Chemistry vol. 511 issue 1-2 April 5, 1996. p. 293-298

 CH2FMe2SiBr (II) was prepared by the reaction of CH2FMe2SiH with Br2. The solvolysis… (more)

Keywords: Silylamides

ISSN: 0022-328X.

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23. O-Benzylated-calix[4]arenes as ancillary ligands in organolanthanide chemistry. Estler, Frank; Herdtweck, Eberhardt; Anwander, Reiner. Journal of the Chemical Society, Dalton Transactions vol. 2002 issue 16 August 8, 2002. p. 3088-3089

 25,27-O-Benzylated-calix[4]arenes H2L react with Ln[N(SiHMe2)2]3(thf)x (Ln = Sc (x = 1), Lu (x… (more)

Keywords: silylamide

DOI: 10.1039/b205200h. ISSN: 1477-9226.

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24. Synthesis and Structure of Aminopyridinato-Stabilized Yttrium and Lanthanum Amides and Their Reactivity towards Alkylaluminium Compounds. Döring, Christian; Kempe, Rhett. European Journal of Inorganic Chemistry vol. 2009 issue 3 January 2009. p. 412 - 418

 A series of aminopyridinato-stabilized (amido)lanthanide complexes has been synthesized and characterized. The bulky… (more)

Keywords: Aluminium; N ligands; Ligand transfer; Rare earths; Silylamide route

DOI: 10.1002/ejic.200800934. ISSN: 1434-1948.

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25. The First Oligomeric Samarium(II) Silylamide: Coordinative Saturation through Agostic Sm···SiH Interactions. Nagl, Iris; Scherer, Wolfgang; Tafipolsky, Maxim; Anwander, Reiner. European Journal of Inorganic Chemistry vol. 1999 issue 9 September 1999. p. 1405 - 1407

  Sm[N(SiMe3)2]2(thf)2 reacts with 1,1,3,3-tetramethyldisilazane by a transsilylamination reaction to form the hexane-soluble… (more)

Keywords: Agostic interactions; Samarium; Silylamide; Transsilylamination; Trinuclear complex

DOI: 10.1002/(SICI)1099-0682(199909)1999:9<1405::AID-EJIC1405>3.0.CO;2-#. ISSN: 1434-1948.

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26. Syntheses and Crystal Structures of Novel Functionalized Lithium Silylamides R(4–n)Si(N(Li)CH2CH2NR'2)n (R = Me, Ph, R' = Me, iPr; n = 2, 3). Lechner, Bob‐Dan; Hahn, Sven; Wagner, Christoph; Merzweiler, Kurt. Zeitschrift für anorganische und allgemeine Chemie vol. 639 issue 14 November 2013. p. 2597-2603

 The difunctional aminosilanes Ph2Si(NHCH2CH2NMe2)2 (1), Me2Si(NHCH2CH2NiPr2)2 (2) and Ph2Si(NHCH2CH2NiPr2)2 (3) were prepared by… (more)

Keywords: Silylamide

DOI: 10.1002/zaac.201300372. ISSN: 0044-2313.

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27. Donor and ate-Coordination in Rare-Earth Metal Bis(dimethylsilyl)amide Complexes. Meermann, Christian; Gerstberger, Gisela; Spiegler, Michael; Törnroos, Karl W.; Anwander, Reiner. European Journal of Inorganic Chemistry vol. 2008 issue 12 April 2008. p. 2014 - 2023

 Complete thf donor exchange is observed when complexes Ln[N(SiHMe2)2]3(thf)2 (Ln = La, Nd)… (more)

Keywords: Silylamide

DOI: 10.1002/ejic.200800050. ISSN: 1434-1948.

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28. Growth of Praseodymium Oxide and Praseodymium Silicate Thin Films by Liquid Injection MOCVD. Aspinall, H.C.; Gaskell, J.; Williams, P.A.; Jones, A.C.; Chalker, P.R.; Marshall, P.A.; Smith, L.M.; Critchlow, G.W. Chemical Vapor Deposition vol. 10 issue 2 March, 2004. p. 83 - 89

 Thin films of praseodymium oxide have been deposited by liquid injection MOCVD using… (more)

Keywords: Silylamide ligand

DOI: 10.1002/cvde.200306282. ISSN: 0948-1907.

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29. Kristallstruktur des Zinkamids Zn[N(SiMe3)2]2. Margraf, G.; Lerner, H.-W.; Bolte, M.; Wagner, M. Zeitschrift für anorganische und allgemeine Chemie vol. 630 issue 2 February 2004. p. 217 - 218

 Crystal Structure of the Zinc Amide Zn[N(SiMe3)2]2X-ray quality crystals of Zn[N(SiMe3)2]2 (monoclinic, P21/c)… (more)

Keywords: Silylamide

DOI: 10.1002/zaac.200300293. ISSN: 0044-2313.

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30. Low-temperature preparation of crystalline barium sulfide. Tang, Yongjun; Dunphy, Darren R.; Kemp, Richard A. Applied Organometallic Chemistry vol. 19 issue 6 June 2005. p. 803 - 805

 Barium sulfide (BaS) is a compound with many uses, both commercially and in… (more)

Keywords: silylamides

DOI: 10.1002/aoc.890. ISSN: 0268-2605.

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