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1. Kinetic Studies of the Oxidative Addition and Transmetallation Steps Involved in the Cross-Coupling of Alkynyl Stannanes with Aryl Iodides Catalysed by η2-(Dimethyl fumarate)(iminophosphane)palladium(0) Complexes. Crociani, Bruno; Antonaroli, Simonetta; Canovese, Luciano; Uguagliati, Paolo; Visentin, Fabiano. European Journal of Inorganic Chemistry vol. 2004 issue 4 February 2004. p. 732 - 742

 The complexes [Pd(η2-dmfu)(P−N)] {dmfu = dimethyl fumarate; P−N = 2-(PPh2)C6H4−1-CH=NR, R = C6H4OMe-4… (more)

Keywords: Palladium; N,P ligands; Kinetics; Cross-coupling

DOI: 10.1002/ejic.200300376. ISSN: 1434-1948.

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2. Structural studies on iminophosphine ligands and their palladium complexes. Bandoli, Giuliano; Dolmella, Alessandro; Crociani, Laura; Antonaroli, Simonetta; Crociani, Bruno. Transition Metal Chemistry vol. 25 issue 1 February 2000 - April 2000. p. 17-25

 The crystal and molecular structures of the iminophosphine o-(Ph_2P)C_6H_4CH=NC_6H_4OMe-4 (1) and its palladium… (more)

ISSN: 0340-4285.

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3. Insertion of methyl isonitrile into niobium- and tantalum-chlorine bonds. Crociani, Bruno; Richards, Raymond L. Journal of the Chemical Society, Chemical Communications vol. 1973 issue 4 1973. p. 127b-128

Methyl isonitrile inserts into the metal-chlorine bond of niobium and tantalum pentachlorides to give [MCI4{C(CI)[z.dbd]NMe} (MeNC)]; (M = Nb or Ta) and [NbCI3{C(CI)[z.dbd]NMe}2(CNMe)];; the complex [NbCI3{C-(CI)[z.dbd]NMe}2PPh3]; has also been prepared.

DOI: 10.1039/C3973000127b. ISSN: 0022-4936.

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4. Palladium complexes of 8-(di-tert-butylphosphinooxy) quinoline. Crociani, Bruno; Antonaroli, Simonetta; Burattini, Marcello; Benetollo, Franco; Scrivanti, Alberto; Bertoldini, Matteo. Journal of Organometallic Chemistry vol. 693 issue 26 December 15, 2008. p. 3932-3938

 The preparation of the new ligand 8-(di-tert-butylphosphinooxy)quinoline (1) and the palladium derivatives [PdCl2(1)]… (more)

Keywords: Palladium organometallic complexes; Phosphinito–quinoline ligands; Solution and solid state structure; Suzuki–Miyaura reaction

DOI: 10.1016/j.jorganchem.2008.10.001. ISSN: 0022-328X.

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5. Structural studies on iminophosphine ligands and their palladium complexes. Bandoli, Giuliano; Dolmella, Alessandro; Crociani, Laura; Antonaroli, Simonetta; Crociani, Bruno. Transition Metal Chemistry vol. 25 issue 1 February 2000 - April 2000. p. 17-25

 The crystal and molecular structures of the iminophosphine o-(Ph_2P)C_6H_4CH=NC_6H_4OMe-4 (1) and its palladium… (more)

ISSN: 0340-4285.

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6. Electrochemical investigations of cationictrans-haloarylisocyanidebis(tertiaryphosphino)platinum (II) complexes. Zanello, Piero; Seeber, Renato; Crociani, Bruno; Nicolini, Marino. Transition Metal Chemistry vol. 5 issue 1 December 1980. p. 45 - 48

 Summary The electrochemical behaviour of a series of cationic platinum(II) isocyanide complexes has… (more)

DOI: 10.1007/BF01396866. ISSN: 0340-4285.

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7. Electrochemical behaviour ofcis-dichloro(arylisocyanide)(tertiaryphosphine) platinum (II) and palladium(II) complexes in an aprotic solvent. Zanello, Piero; Seeber, Renato; Cinquantini, Arnaldo; Crociani, Bruno. Transition Metal Chemistry vol. 5 issue 1 December 1980. p. 226 - 229

 Summary The electrochemical behaviour of neutral platinum(II) and palladium(II) isocyanide complexes has been… (more)

DOI: 10.1007/BF01396920. ISSN: 0340-4285.

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8. Highly efficient Heck olefin arylation in the presence of iminophosphine–palladium(0) complexes. Scrivanti, Alberto; Bertoldini, Matteo; Matteoli, Ugo; Beghetto, Valentina; Antonaroli, Simonetta; Marini, Alessia; Crociani, Bruno. Journal of Molecular Catalysis. A, Chemical vol. 235 issue 1-2 July 1, 2005. p. 12-16

 The Heck coupling of aryl bromides with olefins such as styrene or butyl… (more)

Keywords: Palladium; Iminophosphine–palladium(0) complexes; Heck reaction; Aryl bromides

DOI: 10.1016/j.molcata.2004.12.007. ISSN: 1381-1169.

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9. Kinetics and mechanism of regioselective amination of the 1-phenylallyl group in cationic palladium(II) complexes bearing bidentate ligands. Crociani, Bruno; Antonaroli, Simonetta; Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo. Inorganica Chimica Acta vol. 315 issue 2 April 27, 2001. p. 172 - 182

 The complexes [Pd(η3-1-PhC3H4)(L–L′)]+ [L–L′=2-(PPh2)C6H4-1-CH[z.dbnd6]NR (R=Me (1a), i-Pr (1b), t-Bu (1c), (R)-bornyl (1d), C6H4OMe-4… (more)

Keywords: Kinetics and mechanism; Amination; Palladium complexes; Allyl complexes

ISSN: 0020-1693.

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10. Mechanism of aminocarbene formation by nucleophilic attack on isocyanide ligands in platinum(II) 2-pyrazyl and 4-pyridyl complexes. Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo; Crociani, Bruno; Di Bianca, Franca. Journal of Organometallic Chemistry vol. 535 issue 1-2 May 15, 1997. p. 69-75

 The reactions of 2-pyrazyl and 4-pyridyl isocyanide complexes [Pt(CNC6H11)(C4H3N2-C2)(dppe)ClO4 and [Pt(CNC6H11)(C5H4N-C4)(dppe)]ClO4 (1) with… (more)

Keywords: Kinetics and mechanism; Platinum complexes; Isocyanide complexes; Carbene complexes; Nucleophilic attacks

ISSN: 0022-328X.

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11. Mechanism of formation of (methoxy)(amino)- and bis(amino) carbene complexes by nucleophilic attack of methoxide ion and amines on platinum(II) -coordinated isocyanide in anhydrous methanol. Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo; Crociani, Bruno. Journal of Organometallic Chemistry vol. 543 issue 1-2 September 30, 1997. p. 145-151

 The isocyanide complexes [Pt(CNC6H11)(R)(dppe)]ClO4 (R = C4H3N2-C2, 2-pyz; C5H4N-C4, 4-py) undergo nucleophilic attack… (more)

ISSN: 0022-328X.

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12. Mechanism of oxidative allyl transfer from allylic ammonium cations to palladium(0) α-diimine complexes. Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo; Di Bianca, Francesca; Fontana, Alberta; Crociani, Bruno. Journal of Organometallic Chemistry vol. 508 issue 1-2 February 8, 1996. p. 101-108

 The palladium(0) complex [Pd(η2-fn)(N – N′)] (1, fn = fumaronitrile; N – N′ = C5H4N-2-CH=NC6H4OMe-4)… (more)

Keywords: Palladium; Allyl transfer; Kinetic studies

ISSN: 0022-328X.

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13. Preparation and reactions of palladium(0)–olefin complexes with iminophosphine ligands. Antonaroli, Simonetta; Crociani, Bruno. Journal of Organometallic Chemistry vol. 560 issue 1-2 June 15, 1998. p. 137-146

 The complexes [Pd(η2-ol){o-(Ph2P)–C6H4–CH[z.dbnd6]NR}] [ol, dimethyl fumarate (dmf), 1,4-naphtoquinone (nq), fumaronitrile (fn); R=C6H4OMe-4, CMe3,… (more)

Keywords: Palladium; Alkene complexes; Olefin rotation; Oxidation addition

ISSN: 0022-328X.

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14. Convenient synthesis of cationic allylplatinum(II) complexes with tertiary phosphines by oxidative allyl transfer from ammonium cations to platinum(0) substrates. Crystal and molecular structures of η3-propenyl- and η3-2-methylpropenyl-bis(triphenylphosphine)platinum(II)perchlorates. Crociani, Bruno; Benetollo, Franco; Bertani, Roberta; Bombieri, Gabriella; Meneghetti, Fiorella; Zanotto, Livio. Journal of Organometallic Chemistry vol. 605 issue 1 June 30, 2000. p. 28 - 38

 A large variety of cationic η3-allylplatinum(II) complexes of the type [Pt(η3-CH2C(R)C(R′)(R″)(PPh3)2]+ (1a–f) are… (more)

Keywords: Synthesis; Platinum; Allyl complexes; X-ray structures

ISSN: 0022-328X.

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15. Conformational flexibility and molecular dynamics of cationic diolefin–rhodium(I) complexes with iminophosphine ligands. Crociani, Bruno; Antonaroli, Simonetta; Di Vona, Maria Luisa; Licoccia, Silvia. Journal of Organometallic Chemistry vol. 631 issue 1-2 August 10, 2001. p. 117 - 124

 In solution, the cationic complexes [Rh(η2,η2-diolefin)(P[z.sbnd]N)]+ [diolefin=1,5-cyclooctadiene (cod), bicyclo[2.2.1]hepta-2,5-diene (nbd); P[z.sbnd]N=o-(PPh2)C6H4CH[z.dbnd6]NR (R=C6H3(i-Pr)2-2,6 (1),… (more)

Keywords: Solution dynamics; [Rh(η22-diolefin)(iminophosphine)]+; 2D-exchange NMR; Semi-empirical calculations

ISSN: 0022-328X.

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16. Catalytic activity of η2-(olefin)palladium(0) complexes with iminophosphine ligands in the Suzuki–Miyaura reaction. Role of the olefin in the catalyst stabilization. Scrivanti, Alberto; Beghetto, Valentina; Matteoli, Ugo; Antonaroli, Simonetta; Marini, Alessia; Crociani, Bruno. Tetrahedron vol. 61 issue 41 October 10, 2005. p. 9752-9758

 The catalytic activity of η2-(olefin)palladium(0)(iminophosphine) complexes in the Suzuki–Miyaura coupling is strongly dependent… (more)

Keywords: Suzuki–Miyaura reaction; Iminophosphine complexes; Palladium; Arylboronic acids; Biaryls; Cross-coupling

DOI: 10.1016/j.tet.2005.06.079. ISSN: 0040-4020.

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17. Synthesis and reactivity of novel palladium(II)-isocyanide complexes. Crociani, Bruno; Boschi, Tristano; Belluco, Umberto. Inorganic Chemistry vol. 9 issue 9 1970. p. 2021-2025

DOI: 10.1021/ic50091a013. ISSN: 0020-1669.

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18. Configuration of imino carbon palladated pyridine-2-carbaldimines. Crystal and molecular structure of trans-chlorobis(dimethylphenylphosphine)[(p-methoxyphenyl)imino](2-pyridyl)methyl]palladium(II). Crociani, Bruno; Sala, Marcellina; Polo, Adriano; Bombieri, Gabriella. Organometallics vol. 5 issue 7 1986. p. 1369-1376

DOI: 10.1021/om00138a012. ISSN: 0276-7333.

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19. Solution Behavior and X-ray Structure of Cationic Allylpalladium(II) Complexes with Iminophosphine Ligands. Kinetics and Mechanism of Allyl Amination by Secondary Amines. Crociani, Bruno; Antonaroli, Simonetta; Boli, Giuliano; Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo. Organometallics vol. 18 issue 7 March 29, 1999. p. 1137-1147

DOI: http://dx.doi.org/10.1021/om980858l. ISSN: 0276-7333.

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20. Isomer Distribution and Interconversion in Cationic Allylpalladium(II) Complexes with 2-(Iminomethyl)pyridine Ligands. Crociani, Bruno; Antonaroli, Simonetta; Paci, Maurizio; Bianca, Francesca Di; Canovese, Luciano. Organometallics vol. 16 issue 3 February 04, 1997. p. 384-391

DOI: http://dx.doi.org/10.1021/om9608420. ISSN: 0276-7333.

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21. 1H nuclear magnetic resonance spectra of carbene complexes of platinum(II) and palladium(II). Crociani, Bruno; Richards, Raymond L. Journal of the Chemical Society, Dalton Transactions vol. 1974 issue 7 1974. p. 693-697

 The 1H n.m.r. spectra of the complexes cis-[MCl2{C(NHR1)(NR2R3)}(PR3)];, trans-[PtCl{C(NHR1) (NR2R3)}(PR3)2];ClO4, cis-[MCl2{C(OR4)(NHR1)}(PR3)];, and trans-[MCl{C(OR4)(NHR1)}(PR3)2];ClO4… (more)

DOI: 10.1039/DT9740000693. ISSN: 1477-9226.

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22. Insertion of lsocyanides into niobium– and tantalum–halogen bonds. Behnam-Dahkordy, Mahbobeh; Crociani, Bruno; Richards, Raymond L. Journal of the Chemical Society, Dalton Transactions vol. 1977 issue 20 1977. p. 2015-2020

 Isocyanides RNC (R = Me or But) insert into the metal–halogen bond of… (more)

DOI: 10.1039/DT9770002015. ISSN: 1477-9226.

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23. 1,2-Bis(arylimino)propylpalladium complexes as N-donor chelate ligands towards metals of the first transition series. Crociani, Bruno; Nicolini, Marino; Richards, Raymond L. Journal of the Chemical Society, Dalton Transactions vol. 1978 issue 11 1978. p. 1478-1484

 1,2-Bis(arylimino)propylpalladium(II) complexes of the type trans-[PdX{C(NR)CMe(NR)}L2]; (X = Cl or Br; R =… (more)

DOI: 10.1039/DT9780001478. ISSN: 1477-9226.

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24. Reactions of palladium(II) allyl dimers with palladium(II) complexes containing σ-bonded 1,2-bis(imino)alkyl groups. Crystal and molecular structure of the zwitterionic binuclear compound [Pd(η3-2-MeC3H4){R1N[z.dbd6]C(PdCl2L)–CMe[z.dbd6]NR2}]; (L = PPh3, R1 = R2 = C6H4OMe-p). Crociani, Bruno; Bertani, Roberta; Boschi, Tristano; Bandoli, Giuliano. Journal of the Chemical Society, Dalton Transactions vol. 1982 issue 9 1982. p. 1715-1728

 The 1,2-bis(imino)alkylpalladium derivatives (A), R1N[z.dbd6]CL′–CR3[z.dbd6]NR2 [R1 = R2 = C6H4OMe-p, R3 = Me,… (more)

DOI: 10.1039/DT9820001715. ISSN: 1477-9226.

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25. Mechanism of migration of ancillary ligands in binuclear palladium(II) allyl complexes. Crociani, Bruno; Uguagliati, Paolo; Belluco, Umberto; Nicolini, Marino. Journal of the Chemical Society, Dalton Transactions vol. 1982 issue 12 1982. p. 2303-2308

 The kinetics and mechanism of the reaction between the binuclear cationic complexes [L2ClPd{C([z.dbd6][graphic… (more)

DOI: 10.1039/DT9820002303. ISSN: 1477-9226.

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26. Preparation and co-ordination properties of trans-chloro-[1-(p-methoxyphenylimino)-2-(methylimino)propyl];bis(triphenylphosphine)-platinum. Crystal and molecular structure of the ionic compound [PtCl{C([z.dbd]NR)CMe[z.dbd]NMe[Rh(CO)2];}(PPh3)2];[RhCl2(CO)2]; (R = C6H4OMe-p). Mantovani, Antonio; Pelloso, Mario; Bandoli, Giuliano; Crociani, Bruno. Journal of the Chemical Society, Dalton Transactions vol. 1984 issue 10 1984. p. 2223-2232

 The 1,2-bis(imino)propyl complex trans-[PtCl{[graphic omitted]Me[z.dbd]NR′}(PPh3)2]; (2) (R = C6H4OMe-p, R′ = Me) can… (more)

DOI: 10.1039/DT9840002223. ISSN: 1477-9226.

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27. Five-coordinate complexes of palladium(ii) and platinum(ii) with α-diimine and 1,5-cyclooctadiene ligands. Bianca, Francesca Di; Bandoli, Giuliano; Dolmella, Alessandro; Antonaroli, Simonetta; Crociani, Bruno. Journal of the Chemical Society, Dalton Transactions vol. 2002 issue 2 January 10, 2002. p. 212-217

 The five-coordinate complexes [PtMe(cod)(N–N′)]BF4 [cod = η2,η2-cyclooctadiene, N–N′ = (6-R2)C5H3N-2-CH[z.dbd]NR1 (R1 = C6H4OMe-4,… (more)

Keywords: five-coordination; palladium; platinum; solution studies; X-ray diffraction, X-ray powder diffraction

DOI: 10.1039/b106247f. ISSN: 1472-7773.

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28. Mechanistic study on the coupling reaction of aryl bromides with arylboronic acids catalyzed by (iminophosphine)palladium(0) complexes. Detection of a palladium(ii) intermediate with a coordinated boron anion. Crociani, Bruno; Antonaroli, Simonetta; Marini, Alessia; Matteoli, Ugo; Scrivanti, Alberto. Dalton Transactions vol. 2006 issue 22 May 30, 2006. p. 2698-2705

 The complexes [Pd(η2-dmfu)(P–N)] [P–N = 2-(PPh2)C6H4-1-CH[z.dbd]NR, R = C6H4OMe-4; CHMe2; C6H3Me2-2,6; C6H3(CHMe2)-2,6] react… (more)

DOI: 10.1039/b514405a. ISSN: 1477-9226.

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29. Phenylation of cationic allyl palladium(II) complexes by tetraphenylborate. Synthesis of α-diimine olefin palladium(0) complexes and mechanistic aspects. Crociani, Bruno; Di Bianca, Francesca; Uguagliati, Paolo; Canovese, Luciano; Berton, Adriano. Journal of the Chemical Society, Dalton Transactions vol. 1991 issue 1 1991. p. 71-79

 The cationic allyl complexes [Pd(η3-2-R1C3H4)(N–N′)];+ (N–N′ = α-diimine ligand; R1 = H or… (more)

DOI: 10.1039/DT9910000071. ISSN: 1477-9226.

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30. Nucleophilic attack at co-ordinated isocyanides promoted by the 2-pyridyl ligand. Crociani, Bruno; Di Bianca, Francesca; Fontana, Alberta; Forsellini, Eleonora; Bombieri, Gabriella. Journal of the Chemical Society, Dalton Transactions vol. 1994 issue 4 1994. p. 407-414

 The co-ordinated isocyanide in the 2-pyridyl intermediate [Pt(CNR) (C5H4N-C2)(dppe)];+ [R = C6H4-OMe-4, dppe… (more)

DOI: 10.1039/DT9940000407. ISSN: 1477-9226.

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